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II: Emergency Response

Recommended Procedure for Cleaning Up a Liquid Chemical Spill

To contain and control a liquid chemical spill, the following procedure works well. First, remove all unprotected personnel and students away from spill. If the spilled chemical is volatile, ventilate the area or evacuate. If the spilled chemical is flammable, remove all ignition sources. Wear personal protection equipment such as chemical splash goggles, chemical–resistant gloves and apron.

Gently pour sand around the spill and onto the spill. The sand will contain the spill, prevent it from spreading, and also provide traction if you need to walk over it. Next, pour absorbent (kitty litter, oil absorbent) around the spill and onto the spill. This will absorb the liquid and also begin to contain any vapors. For both the absorbent and sand, it is best to gently drop or sprinkle the spill control material around the spill and then onto the spill to avoid further spreading. Lastly, if the spill is an inorganic acid or base, apply the appropriate neutralizer around the spill and onto the spill. The neutralizer needs to be mixed well with the sand and absorbent to come in contact with all of the spilled chemical—use a plastic broom to mix well.

After the spill is controlled, the cleanup begins. If the material is warm or still giving off vapors, ventilate the room and wait before cleaning up. Use a plastic dustpan and plastic broom to sweep up the now solid mess and place it into large, heavy–duty plastic garbage or leaf bags for disposal. If at any time during the chemical spill containment or cleanup step you don't feel comfortable, leave the area and get help.     © 2006 Flinn Scientific, Inc. All Rights Reserved. Reproduction permission is granted to science teachers who are current customers of Flinn Scientific, Inc. No part of this material may be reproduced or transmitted in any form or by any means, electronic or mechanical, including, but not limited to photocopy, recording, or any information storage and retrieval system, without permission in writing from Flinn Scientific, Inc.

PREVENTING CHEMICAL SPILLS

Introduction:

No matter what precautions are taken, accidental chemical spills will occur in a science laboratory. Be a responsible science teacher and make sure proper safety equipment is available to contain and control a spill and understand how to use the safety equipment. Equally as important as knowing how to clean up spills is understanding how to prevent both minor and major chemical spills. Experiments, laboratories, and purchasing procedures should be designed to minimize the possibility of chemical spills. Experiments should use the minimal amount of chemicals whenever possible. The following guidelines will reduce the risk of chemical spills.

Purchase of Chemicals:

  • Purchase, store, and dispense chemicals from the smallest bottle possible. For example, do not order or dispense from a 500-mL bottle if each student only needs 1 mL.
  • Purchase, store, and dispense chemicals in unbreakable plastic or PVC-coated glass bottles. Elemental mercury and volatile toxic chemicals must never be stored in uncoated glass bottles. Purchase all concentrated acids in PVC-coated glass bottles.
  • Purchase and store highly toxic or reactive materials in a secondary containment device, such as a Chem-Saf ® bag (heavy-duty plastic bag) or a Saf-Stor ® can (an unused metal paint can).

Storage of Chemicals:

  • Store all flammable liquids in a flammable cabinet and all acids and bases in a wooden acid cabinet. Flammable and acid cabinets must have a 2" high, liquid-tight trough to contain spills and provide secondary containment.
  • Do not store chemicals on the floor, in aisles, stairwells, fume hoods, or on laboratory benches, or anywhere the bottle can be knocked over.
  • Attach a two-inch shelf lip to all chemical storage shelves to prevent bottles from rolling off the shelf. Make your own shelf lips from wood molding or purchase chemical-resistant plastic shelf lips from Flinn.
  • Store chemicals at or below eye level.
  • Check chemical containers periodically for rust, corrosion, and leakage. Some chemicals absorb moisture and will expand until the container splits open.

Dispensing of Chemicals:

  • Dispense chemicals from a central location (preferably a fume hood) and place all reagent bottles on a spill containment tray or absorbent chemical pads. Most plastic cafeteria trays are chemical-resistant and make good containment trays. A large demonstration tray (76 cm L x 51 cm W x 5 cm D) and chemical absorbent pads are available from Flinn.
  • Always use a spatula and weighing boat when weighing out chemicals.
  • Consider attaching a test tube to the side of chemical dispensing bottles to store the dispensing pipet.
  • Use microscale experiments whenever possible.
  • Always recap chemical bottles immediately after use to reduce spillage if the bottle is tipped over.
  • Perform all experiments using highly toxic or corrosive chemicals in work areas designed to contain accidental releases (e.g., use secondary containment trays in a fume hood.)

If the above suggestions are followed, the number of minor spills should decrease and the probability of a major spill will be greatly reduced. However, it is important to regularly review the proper procedures for cleaning up chemical spills and to maintain an adequate supply of spill control materials. For information on how to clean up chemical spills, please request Safety Fax! #10312.

For more information on laboratory safety, chemical hazards, or the storage and disposal of chemicals, consult your current edition of the Flinn Chemical & Biological Catalog/Reference Manual. This resource contains hundreds of helpful How To Boxes and safety tips, and over 100 pages of reference information. Depend on Flinn to provide the latest safety information and to be your problem solving source.

Source: http://www.flinnsci.com/Sections/Safety/chemicalSafety/chemicalSpills.asp

Download Sample Emergency Response Plan (DOC)

 

 

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